No big value as the card can no longer be made. Someone with an actual copy of the redeemed card might also want the redemption card to go along with it as a sidepiece, but probably not very likely. Or some super collector might want it as-is. But big value? I wouldn't think so. If it is one of those thin cardboard ones with the sticker and description and nothing else to it, I'd say zero value.
A bit of the reverse of this: eons ago, I pulled a /100 expired redemption from an old pack and then, years later, I picked up one of the redeemed copies, simply to make that feeling that I missed out on the card go away. And so I then had both. Only 63 copies of card actually got redeemed. These were BAP redemptions which looked like actual cards with gloss, foil embossing and hand-numbering. Normally those redemption cards were kept by the manufacturer, I think, so that's what made it neat to me - you're not supposed to have both.
I also did this with the 1993/94 Alexandre Daigle Score Redemption card, where I got both the SP card and the redemption for it. The redemption cards were a buck or less, so why not?
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